The two sides have already met twice this season, with both teams scoring on both occasions.
Cups odds, betting tips, news and stats
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Stoke are not in great form but a vociferous crowd at the Britannia can make it a difficult night for Valencia.
Back improving Millwall to take Premier League strugglers Bolton to a 5th round replay at football betting odds of 11/5.
Both Everton and Blackpool have been in fine form in recent weeks and are likely to cancel each other out in a captivating tie.
Bank on wins for Man United, Schalke and Udinese as the Europa League returns in full on Thursday.